Calculator · Thermal Engineering

Polytropic Process Calculator

A quasi-equilibrium ideal-gas process that follows pvⁿ = constant. One index covers constant pressure (n = 0), constant temperature (n = 1) and reversible adiabatic (n = γ). Constant volume is its own mode here, never an infinite n.

Inputs

Pressure is absolute (from vacuum) and temperature is absolute (kelvin). No atmospheric pressure is added and no Celsius value is converted behind the scenes.

Results

Boundary work W (by the gas)

-176.75 kJ

ΔU = Q − W. Q > 0 is heat added to the gas; W > 0 is boundary work done by the gas on its surroundings, so a compression has W < 0.

ProcessGeneral polytropic
Polytropic index n1.3
PropertyState 1State 2
p (abs)100 kPa800 kPa
T300 K484.76 K
v0.861 m³/kg0.17391 m³/kg
Boundary work W (by the gas)-176.75 kJ
Heat Q (into the gas)-44.188 kJ
ΔU132.57 kJ
ΔH185.59 kJ
First-law residual Q − W − ΔU0 J

Assumptions

  • · ideal gas
  • · constant specific heats
  • · quasi-equilibrium closed system

Explore in the Lab

Open this process in the Thermodynamic Process Lab

The full process state travels; the Lab adds the P–v diagram.

Technical reference

p vⁿ = const, T2/T1 = (v1/v2)ⁿ⁻¹

W = m R (T2 − T1)/(1 − n), n ≠ 1

W = m R T1 ln(V2/V1), n = 1

ΔU = m cv ΔT, ΔH = m cp ΔT, Q = ΔU + W

n
polytropic index[-]
W
boundary work done by the gas[J]
Q
heat added to the gas[J]
γ
cp/cv[-]

ΔU = Q − W. Q > 0 is heat added to the gas; W > 0 is boundary work done by the gas on its surroundings, so a compression has W < 0.

With n = 0 a final pressure cannot fix the end state, so the volume ratio must be used.

Defaults: 100 kPa, 300 K air compressed with n = 1.3.

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